Eco-friendly smart hydrogels for soil conditioning and sustain release fertilizer     

J. Pushpamalar  S. J. Langford  M. B. Ahmad  Y. Y. Lim  K. Hashim 《International Journal of Environmental Science and Technology》2018,15(10):2059-2074

In the agricultural industry, biomass waste generated along with the production of food, is transformed into value-added products. Also, the demand for the slow or control release fertilizer is increasing to reduce the cost of maintaining the agricultural land. These issues are tackled by converting biomass waste to a slow fertilizer release vehicle and biodegradable water retention material that could reduce the cost for fertilizer application and simultaneously preserved the soil from dryness. A series of carboxymethyl sago pulp (CMSP) hydrogels were prepared by electron beam irradiation. Slow release systems were evaluated by loading potassium nitrate (KNO₃) and ammonium nitrate (NH₄NO₃) into the CMSP hydrogels. These CMSP hydrogels endow slow release property, biodegradability and a soil moisture preservation property that could find greener application in agricultural industries. The results indicate that CMSP hydrogels have a great potential as an agent for slow release of fertilizers.  相似文献   

The effect of traffic on levels,distribution and chemical partitioning of harmful metals in the street dust and surface soil from urban areas of Tehran,Iran     

Ahmad Jonidi Jafari  Majid Kermani  Roshanak Rezaei Kalantary  Hossein Arfaeinia 《Environmental Earth Sciences》2018,77(2):38

Due to the explosive industrialization and rapid expansion of the population in many parts of the world, heavy metals are released into the environment continuously and pose a great risk on human health. Street dust and surface soil samples from very heavy, heavy, medium and low traffic areas and a natural site in Tehran, Iran, were analyzed for some physicochemical features, total and chemical fractionating of selected metals (Zn, Al, Sr, Pb, Cu, Cr, Cd, Co, Ni and V) to investigate the influence of traffic on their mobility and accumulation in the environment. The pH, electrical conductivity (EC), carbonates and organic carbon contents were similar in soil and dust samples from the areas with same traffic. The traffic increases EC contents in dust/soil matrixes, but has no effect on concentrations of metals in soil samples. Rises in metal levels with traffic were found in dust samples. Moreover, the traffic increases the percentage of both acid-soluble and reducible fractions, which are related to Pb and Zn. The mobilization of Cu, Zn, Pb, Cr in dust samples was easier than in soil. The speciation of metals except Cd is mainly affected by physicochemical features in soil, though total metals affected the speciation in dust samples (except chromium and nickel).  相似文献   

Ghaleh-khargushi rhyodacite and Gorid andesite from Iran: characterization,uses, and durability     

Ahmad Zalooli  David Martín Freire-Lista  Mashalah Khamehchiyan  Mohammad Reza Nikudel  Rafael Fort  Shahram Ghasemi 《Environmental Earth Sciences》2018,77(8):315

Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.  相似文献   

Diagenetic evolution vis-a-vis reservoir characteristics of Dhosa sandstones,Ler dome,Kachchh, western India     

Asma A. Ghaznavi  Mohammad Masroor Alam  Zuhi Khan  A. H. M. Ahmad 《Arabian Journal of Geosciences》2018,11(14):387

The detrital mineralogy as well as diagenetic characters of the Dhosa Sandstone Member of Chari Formation exposed at the Lerdome, south of Bhuj was studied. In order to assess the potential of the Dhosa Sandstone as a reservoir, it is substantial to understand the diagenetic processes that are controlled largely by post-depositional cementation and compaction in addition to framework composition and original depositional textures. The petrologic analysis of 33 thin sections was carried out to discern primary composition and diagenetic features including primary and secondary porosity patterns. Monocrystalline quartz dominates the detrital mineralogy followed by polycrystalline quartz. Among the polycrystalline variety recrystallized metamorphic quartz surpasses stretched metamorphic quartz in terms of abundance. Feldspars comprise microcline and plagioclase where the former is dominant over the latter. Orthoclase too comprises a very small percentage. Mica, chert, rock fragments, and heavies form the remaining detrital constituent in descending order of their constituent percentage. The diagenetic precipitates are mainly carbonate (8.30%) and iron (7.80%) followed by clay (0.66%) and silica (0.88%) that are minor constituent of the total cementing material. The main paragenetic events identified are early cementation, mechanical compaction, late cementation, dissolution, and authigenesis of clays. The overall reservoir quality seems to be controlled by compaction and authigenic carbonate cementation. The minus cement porosity average 29.4%. The porosity loss due to compaction is 21.92% and by cementation is 29.71%. The loss of original porosity was due to early cementation followed by moderate mechanical compaction during shallow burial. Preservation of available miniscule primary porosity was ascribed to dissolution of carbonates and quartz overgrowth which resisted chemical compaction during deep burial. The studied sandstones may have low reservoir quality owing to existing porosity of less than 9%. More carbonate dissolution and its transformation in dolomite in sub-surface condition and macro-fracture porosity may result in enhanced secondary porosity and good diagenetic traps.  相似文献   

Petrology,geochemistry and geodynamic setting of Eocene-Oligocene alkaline intrusions from the Alborz-Azerbaijan magmatic belt,NW Iran     

Nasser Ashrafi  Ahmad Jahangiri  Noriko Hasebe  G. Nelson Eby 《Chemie der Erde / Geochemistry》2018,78(4):432-461

The Kaleybar, Razgah and Bozqush (KRB) intrusions were studied to better understand subduction-related Eocene-Oligocene alkaline magmatism in NW Iran. The bulk of intrusions mainly consist of Si-undersaturated rocks including foid-bearing monzonite and syenite (nepheline syenite, pseudoleucite syenite) with some foid-bearing diorite and gabbro. In addition, they are spatially associated with Si-saturated rocks ranging in composition from monzo-diorite to syeno-granite. The main mafic rock-forming minerals of the studied rocks are olivine (Fo₄₄Fa₅₆), clinopyroxene (diopside to augite), biotite (Mg-biotite through Fe-biotite), amphibole (ferro-pargasite and magnesio-hastingsite with Mg#<0.55), and garnet (Ti-andradites). Based on whole rock geochemistry, the foid-syenites and associated rocks show mildly alkaline (shoshonitic) affinity. The content of SiO₂, K₂O?+?Na₂O, and K₂O/Na₂O ratio ranges from 47.8 to 60.7?wt.%, 5.31 to 16.33?wt.%, and 0.6 to 3.2, respectively. The intrusions are commonly metaluminous, with an aluminum-saturation index (ASI) ranging from 0.66 to 1.01. Almost all the rocks display similar arc-related geochemical features characterized by the enrichment in large ion lithophile elements (LILE) and light rare earth elements (LREE) together with the depletion in high field strength elements (HFSE). The chondrite-normalized REE patterns show no to marked negative Eu anomaly (Eu/Eu*?=?0.55 to 1.12), (La/Yb)_N?=?8.16 to 31, (La/Sm)_N?=?2.80 to 10.59, and (Tb/Yb)_N?=?0.84 to 2.40. The evaluation of the REE patterns for the KRB magmas and the comparison of the trace element ratios with experimental studies indicate a chemically enriched lithospheric mantle source composed of garnet-spinel-lherzolite that have underwent a low degree of partial melting <5% to generate the KRB intrusions. Based on the present data, we infer that the mantle source was contaminated by a subduction component and the melting of the mantle lithosphere occurred by local extension in an overall convergent regime in NW Iran. The extension regime during the Eocene is proposed to be the result of the Neo-Tethys slab roll-back and the Sevan-Akera-Qaradagh (SAQ) slab break-off.  相似文献   

Episodic crustal growth in the Bundelkhand craton of central India shield: Constraints from petrogenesis of the tonalite–trondhjemite–granodiorite gneisses and K-rich granites of Bundelkhand tectonic zone     

Hiredya Chauhan  Ashima Saikia  Talat Ahmad 《Journal of Earth System Science》2018,127(3):44

Tonalite–trondhjemite–granodiorite gneisses (TTG) and K-rich granites are extensively exposed in the Mesoarchean to Paleoproterozoic Bundelkhand craton of central India. The TTGs rocks are coarse- grained with biotite, plagioclase feldspar, K-feldspar and amphibole as major constituent phases. The major minerals constituting the K-rich granites are K-feldspar, plagioclase feldspar and biotite. They are also medium to coarse grained. Mineral chemical studies show that the amphiboles of TTG are calcic amphibole hastingsite, plagioclase feldspars are mostly of oligoclase composition, K-feldspars are near pure end members and biotites are solid solutions between annite and siderophyllite components. The K-rich granites have biotites of siderophyllite–annite composition similar to those of TTGs, plagioclase feldspars are oligoclase in composition, potassic feldspars have \(\hbox {X}_{\mathrm{K}}\) ranging from 0.97 to 0.99 and are devoid of any amphibole. The tonalite–trondhjemite–granodiorite gneiss samples have high \(\hbox {SiO}_{2}\) (64.17–74.52 wt%), \(\hbox {Na}_{2}\hbox {O}\) (3.11–5.90 wt%), low Mg# (30–47) and HREE contents, with moderate \((\hbox {La/Yb})_{\mathrm{CN}}\) values (14.7–33.50) and Sr/Y ratios (4.85–98.7). These geochemical characteristics suggest formation of the TTG by partial melting of the hydrous basaltic crust at pressures and depths where garnet and amphibole were stable phases in the Paleo-Mesoarchean. The K-rich granite samples show high \(\hbox {SiO}_{2}\) (64.72–76.73 wt%), \(\hbox {K}_{2}\hbox {O}\) (4.31–5.42), low \(\hbox {Na}_{2}\hbox {O}\) (2.75–3.31 wt%), Mg# (24–40) and HREE contents, with moderate to high \((\hbox {La/Yb})_{\mathrm{CN}}\) values (9.26–29.75) and Sr/Y ratios (1.52–24). They differ from their TTG in having elevated concentrations of incompatible elements like K, Zr, Th, and REE. These geochemical features indicate formation of the K-granites by anhydrous partial melting of the Paleo-Mesoarchean TTG or mafic crustal materials in an extensional regime. Combined with previous studies it is interpreted that two stages of continental accretion (at 3.59–3.33 and 3.2–3.0 Ga) and reworking (at 2.5–1.9 Ga) occurred in the Bundelkhand craton from Archaean to Paleoproterozoic.  相似文献   

The perception of stakeholders on regional transformation on the outskirts of Yogyakarta City,Indonesia     

Sri Rum Giyarsih  Muh Aris Marfai 《GeoJournal》2018,83(5):983-991

The research was conducted on the outskirts of Yogyakarta City that administratively include three districts of Sleman Regency, namely Depok, Gamping, and Mlati, and three districts of Bantul Regency, namely Kasihan, Sewon, and Banguntapan. It aimed to obtain a deeper understanding on the perceptions of stakeholders on the regional transformation phenomena occurring on the outskirts of Yogyakarta City. This is a qualitative case study research with a single case. The case study research method was selected because the observed phenomenon is contemporary and the analyzed issue is unique. It used a qualitative method with field observations and in-depth interviews to several informants as data acquisition techniques. The informants were stakeholders from state/government, private sector/entrepreneur, academics, and civil society, which were selected using purposive sampling method. The research data processing and analysis included: (1) data reduction, (2) data presentation, and (3) data conclusion. In order to examine the reliability and validity of the data, the research used source triangulation method. The results showed that all stakeholders perceived the regional transformation on the outskirts of Yogyakarta City to have positive and negative consequences on various dimensions. The positive ones were the economic opportunities, generated by the regional transformation process, for both the native people and the migrants. Aside from these positive consequences, the regional transformation on the outskirts of Yogyakarta City also caused negative impacts on the physical, economic, social, and cultural dimensions of the outskirts.  相似文献   

An analysis of climatic and human induced determinants of agricultural land use changes in Shupiyan area of Jammu and Kashmir state,India     

Rehana Rasool  Mifta ul Shafiq  Pervez Ahmed  Parvaiz Ahmad 《GeoJournal》2018,83(1):49-60

The economy of the Jammu and Kashmir state depends mostly on traditional forms of occupation. Unaffected and unaltered by modern day industrial developments and changing times, the indigenous traditional occupations of farming, animal husbandry and horticulture forms the backbone of the state economy. But in the last few decades, Agriculture in the state as well as the study area is receiving a set back and Horticulture is flourishing leaps and bounds. The present study aims to analyze various determinants responsible for this change. Climatic as well as field data was thoroughly analyzed to comprehend the situation. A Mann–Kendall test was done on the climatic data to support the hypotheses. It was observed that initially changing climatic trends proved to be the triggering factor supporting this change, but in due course of time, the determinants took an economic and psychological turn. The perusal of Indian Meteorological Data reveals an increasing trend of annual mean maximum temperature from 16.78 °C in 1985 to 17.58 °C in 1995 and an increase from 5.30 °C to 7.00 °C in the annual mean minimum temperature, and as such acting as a triggering factor for the land use conversion. Further, the mean annual rainfall shows a decrease from 100.75 mm in 1981 to 79.43 mm in 1991. The greater economic returns from horticulture as well as the changing behavioral patterns of people over the time further cemented its growth. The farmers have since persisted with the horticulture activity as it has proven to be an economically a much better lucrative enterprise.  相似文献   

Post-eruptive lahars at Kali Putih following the 2010 eruption of Merapi volcano,Indonesia: occurrences and impacts     

Hadmoko  Danang Sri  de Belizal  Edouard  Mutaqin  Bachtiar Wahyu  Dipayana  Gilang Arya  Marfai  Muh Aris  Lavigne  Franck  Sartohadi  Junun  Worosuprojo  Suratman  Starheim  Colette C. A.  Gomez  Christopher 《Natural Hazards》2018,94(1):419-444

Following the 2010 VEI 4 eruption of Merapi volcano, more than 250 lahars were triggered during two rainy seasons from October 2010 to March 2012. This high number of post-eruption lahars mainly occurred in the Kali (valley) Putih watershed and was mostly associated with high-magnitude rainstorms. A lahar occurring on January 8, 2011, caused significant damage to homes in several communities, bridges, sabo dams, and agricultural crops. The aims of this contribution are to document the impacts of lahars on the Kali Putih watershed and specifically (1) to analyze the lahar frequency during the period of 1969–2012 on an inter-annual and intra-annual basis and to determine the link between the volume of tephra and the frequency of lahars; (2) to detail the lahar trajectory and channel evolution following the January 8th lahar; (3) to map the spatial distribution of the thickness and geomorphic effects of the lahar deposit; and (4) to determine the impacts of the lahar on the infrastructure (sabo dams and roads) and settlements in the distal area of the volcano. The Kali Putih watershed has experienced 62 lahars, which represent 22% of all lahars triggered on 17 rivers at Merapi between 2010 and 2012. The main geomorphic impacts are: (1) excessive sedimentation in valleys, settlements and agricultural areas; (2) undercutting of the river banks by as much as 50 m, accompanied by channel widening; and (3) abrupt changes in the river channel direction in the distal area (15–20 km downstream of the volcano). About 19 sabo dams were damaged, and 3 were totally destroyed. Over 307 houses were damaged, and the National Road Yogyakarta–Semarang was regularly cut (18 times during approximately 25 days). Although the sabo dams on Kali Putih were originally constructed to protect distal areas from lahar damage, they had little effect on the 2010–2012 rain-triggered lahars. The underlying design of those dams along this river is one of the main reasons for the major destruction in this sector of the volcano’s lower slope. The catch basin capacity of the sabo dam was only 1.75?×?10⁶ m³, whereas the total volume of the 2010–2011 lahars exceeded 5?×?10⁶ m³. In order to prepare for future lahars, the government has invested in significant mitigation measures, ranging from structural approaches (e.g., building new sabo dams and developing an early warning system) to non-structural approaches (e.g., contingency and preparedness planning and hazard education).

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Selecting Equivalent Strength for Intact Rocks in Heterogeneous Rock Masses     

Mahmoud Behnia  Ahmad Rahmani Shahraki  Zabihallah Moradian 《Geotechnical and Geological Engineering》2018,36(4):1975-1989

Many surface and underground structures are constructed in heterogeneous rock formations. These formations have a combination of weak and strong rock layers. Due to the alternation of the weak and strong layers, selecting the equivalent and appropriate geomechanical parameters for these formations is challenging. One of these problems is choosing the equivalent strength (i.e., uniaxial compressive strength) of intact rock for a group of rocks. Based on the volume of weak and strong parts and their strength, the equivalent strength of heterogeneous rocks changes. Marinos and Hoek (Bull Eng Geol Environ 60(2):85–92, 2001) presented the “weighted average method” for defining the uniaxial compressive strength (UCS) of heterogeneous rock masses based on the volume of weak and strong parts. Laubscher (1977) used the volume ratio of the strength of a weak part to a strong part (UCS weak/UCS strong) to determine the equivalent strength. In this study, the two methods are compared and their validity is evaluated by experimental data and numerical analyses. The geomechanical parameters of two heterogeneous formations (Aghajari and Lahbari) in the west of Iran were estimated using these methods. The results of the present study obtained through numerical analyses using particle flow code are compared with those of previous studies and discussed. Laboratory and numerical results show UCS decrease and approach to weak strength with an increasing in volume of weak part. When strength ratio of strong to weak rock increase, equivalent strength decrease more severely. The findings show that Laubscher’s method gives more appropriate results than the weighted average method.  相似文献